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13 C− 13 C Rotational Resonance Width Distance Measurements in Uniformly 13 C-Labeled Peptides

✍ Scribed by Ramachandran, Ramesh; Ladizhansky, Vladimir; Bajaj, Vikram S.; Griffin, Robert G.


Book ID
125899679
Publisher
American Chemical Society
Year
2003
Tongue
English
Weight
152 KB
Volume
125
Category
Article
ISSN
0002-7863

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The REDOR and CPMAS techniques are applied for measuring 13C-15N dipolar coupling constants in glycine. It is shown that the selective CP or SPECIFIC CP technique removes the coherent evolution of the spin system under homonuclear 13C-13C J couplings. While the large coupling constant (approximately