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Frequency Selective Heteronuclear Dipolar Recoupling in Rotating Solids: Accurate 13 C− 15 N Distance Measurements in Uniformly 13 C, 15 N-labeled Peptides

✍ Scribed by Jaroniec, Christopher P.; Tounge, Brett A.; Herzfeld, Judith; Griffin, Robert G.


Book ID
126316750
Publisher
American Chemical Society
Year
2001
Tongue
English
Weight
234 KB
Volume
123
Category
Article
ISSN
0002-7863

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13C/15N distance determination by CPMAS
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The REDOR and CPMAS techniques are applied for measuring 13C-15N dipolar coupling constants in glycine. It is shown that the selective CP or SPECIFIC CP technique removes the coherent evolution of the spin system under homonuclear 13C-13C J couplings. While the large coupling constant (approximately