In the title compound, C 12 H 15 Cl 2 NO, the piperidine ring adopts a chair conformation. An intramolecular O-HÁ Á ÁN hydrogen bond is observed. The packing of the molecules in the crystal structure is stabilized byinteractions and ClÁ Á ÁCl contacts.
1-(Piperidin-1-ylmethyl)-2-naphthol
✍ Scribed by Liu, Qing-Wei ;Zhang, Ming-Jie ;Wang, Xiang-Qian ;Ma, Peng-Gao
- Publisher
- International Union of Crystallography
- Year
- 2005
- Tongue
- English
- Weight
- 129 KB
- Volume
- 61
- Category
- Article
- ISSN
- 1600-5368
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✦ Synopsis
The title compound, C 16 H 19 NO, is a product of a Mannich reaction involving 2-naphthol, formaldehyde and piperidine. The piperidine ring has a chair conformation. The molecular structure is stabilized by an intramolecular O-HÁ Á ÁN hydrogen bond, linking the naphthol OH group and the piperidine N atom.
📜 SIMILAR VOLUMES
In the title mononuclear nickel(II) complex, [Ni(C 18 H 21- N 2 O)(NCS)], the Ni II atom is four-coordinated by the phenolate O, imine N and amine N atoms of the Schiff base ligand, and by the terminal N atom of a thiocyanate anion in a square-planar geometry. ## Related literature For the coordi
## 2-(Piperidin -2-yImethyI)cycIoa~anoIs have been synthesized by the reaction between 2-picolyliithium and cycloalkene oxides, followed by catalytic hydrogenation of the resulting 2-(pyridin-2-ylmethyI)cycIoaIkanoIs. The configurations of the 2-(piperidin-2-yI-methyI)cycIoaIkanoIs were assigned b