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NMR spectra and stereochemistry of 2-(piperidin-2-ylmethyl)cycloalkanols

✍ Scribed by Michael J. Begley; Trevor A. Crabb; Olive G. Roch

Publisher: John Wiley and Sons
Year: 1986
Tongue: English
Weight: 574 KB
Volume: 24
Category: Article
ISSN: 0749-1581
DOI: 10.1002/mrc.1260240405

No coin nor oath required. For personal study only.

✦ Synopsis

2-(Piperidin

-2-yImethyI)cycIoa~anoIs have been synthesized by the reaction between 2-picolyliithium and cycloalkene oxides, followed by catalytic hydrogenation of the resulting 2-(pyridin-2-ylmethyI)cycIoaIkanoIs. The configurations of the 2-(piperidin-2-yI-methyI)cycIoaIkanoIs were assigned by comparing their 13C and 'H NMR parameters with those of 2-(piperidin-2-yImethyI)cycIohexanols of known (x-ray) configuration.

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