Cyclohexyl 2-(piperidin-1-ylthiocarbonylsulfanyl)acetate
✍ Scribed by Cao, Hua ;Zhao, Hong-Bin ;Liu, Yan-Li ;Zhou, Fu-Hui ;Liu, Jie-Pin
- Publisher
- International Union of Crystallography
- Year
- 2006
- Tongue
- English
- Weight
- 88 KB
- Volume
- 63
- Category
- Article
- ISSN
- 1600-5368
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📜 SIMILAR VOLUMES
The title compound, C 16 H 19 NO, is a product of a Mannich reaction involving 2-naphthol, formaldehyde and piperidine. The piperidine ring has a chair conformation. The molecular structure is stabilized by an intramolecular O-HÁ Á ÁN hydrogen bond, linking the naphthol OH group and the piperidine N
In the molecule of the title compound, C~28~H~42~O~2~, the two cyclohexane rings adopt chair conformations. The olefinic bond and carbonyl group are approximately coplanar.
In the title mononuclear nickel(II) complex, [Ni(C 18 H 21- N 2 O)(NCS)], the Ni II atom is four-coordinated by the phenolate O, imine N and amine N atoms of the Schiff base ligand, and by the terminal N atom of a thiocyanate anion in a square-planar geometry. ## Related literature For the coordi