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1-Aralkylated Tetrahydro-2-benzazepines. Part III. Synthesis from β-tetralones

✍ Scribed by Daniel Berney; Karlheinz Schuh

Publisher
John Wiley and Sons
Year
1976
Tongue
German
Weight
626 KB
Volume
59
Category
Article
ISSN
0018-019X

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✦ Synopsis

Abstract

1‐Benzyl‐tetrahydro‐2‐benzazepin‐3‐ones 4 were prepared by submitting the corresponding 1‐benzyl‐β‐tetralones 3 to the Schmidt reaction. On the other hand, the rearrangement of the tetralones 3 by the Beckmann procedure gave 1‐benzyl‐tetrahydro‐3‐benzazepin‐2‐ones 5. The syntheses of some hexahydrophenanthro‐azepines of types 10 and 15 are also described.

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