𝔖 Bobbio Scriptorium
✦   LIBER   ✦

μ-Oxido-bis({4,4′-dibromo-2,2′-[ethane-1,2-diylbis(nitrilomethylidyne)]diphenolato}manganese(III))

✍ Scribed by Liu, Ying ;Dou, Jianmin ;Niu, Meiju ;Zhang, Xianxi

Publisher
International Union of Crystallography
Year
2007
Tongue
English
Weight
294 KB
Volume
63
Category
Article
ISSN
1600-5368

No coin nor oath required. For personal study only.

✦ Synopsis

The title compound, [Mn~2~(C~16~H~12~Br~2~N~2~O~2~)~2~O], is an unusual dinuclear manganese(III) complex. Each Mn^III^ ion has a distorted square-pyramidal coordination geometry. In the basal plane, the Mn atom is coordinated by two N atoms and two O atoms of the Schiff base ligand. The apical position is occupied by a bridging O^2−^ ion, which links to the other Mn^III^ ion in the complex; this bridging O atom lies on a twofold rotation axis.

📜 SIMILAR VOLUMES

The cocrystal {4,4′-dimethoxy-2,2′-[prop
The cocrystal {4,4′-dimethoxy-2,2′-[propane-1,2-diylbis(nitrilomethylidyne)]diphenolato}methanol(pyridine)manganese(III) hexafluoridophosphate–{4,4′-dimethoxy-2,2′-[ethane-1,2-diylbis(nitrilomethylidyne)]diphenolato}methanol(pyridine)manganese(III) hexafluoridophosphate (1/1)
✍ Habibi, Mohammad Hossein ;Askari, Elham ;Chantrapromma, Suchada ;Fun, Hoong-Kun 📂 Article 📅 2007 🏛 International Union of Crystallography 🌐 English ⚖ 746 KB

The cocrystal {4,4 0 0 0 -dimethoxy-2,2 0 0 0 -[propane-1,2-diylbis(nitrilomethylidyne)]-diphenolato}methanol(pyridine)manganese(III) hexafluoridophosphate-{4,4 0 0 0dimethoxy-2,2 0 0 0 -[ethane-1,2-diylbis-(nitrilomethylidyne)]diphenolato}methanol(pyridine)manganese(III) hexafluoridophosphate (1/1

Di-μ-oxido-bis({2,2′-[propane-1,3-diylbi
Di-μ-oxido-bis({2,2′-[propane-1,3-diylbis(nitrilomethylidyne)]diphenolato}vanadium(IV)) dimethylformamide disolvate
✍ Liu, Ying ;Dou, Jianmin ;Niu, Meiju ;Zhang, Xianxi 📂 Article 📅 2007 🏛 International Union of Crystallography 🌐 English ⚖ 315 KB

In the title compound, [V~2~(C~17~H~17~N~2~O~2~)~2~O~2~]·2C~3~H~7~NO, each V atom is chelated by a Schiff base ligand __via__ two N and two O atoms. The two octahedrally coordinated V atoms are linked by two bridging oxide ligands to give a centrosymmetric dimer.

4,4′-(Ethane-1,2-diyl)dipyridinium di-μ-
4,4′-(Ethane-1,2-diyl)dipyridinium di-μ-citrato-bis[aquacobaltate(II)]
✍ Yu, Jian 📂 Article 📅 2007 🏛 International Union of Crystallography 🌐 English ⚖ 313 KB

The anion of the title complex, (C~12~H~14~N~2~)[Co~2~(C~6~H~4~O~7~)~2~(H~2~O)~2~], is a centrosymmetric edge-shared bioctahedral dimer, in which the two Co atoms are bridged by two alkoxide O atoms of the fully deprotonated citrate ligands. All of the carboxylate groups coordinate in a monodentate