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Bis{μ-2′-[1-(4-chloro-2-oxido­phenyl)­ethyl­idene]­thio­phene-2-carbohydrazidato}bis­[pyridine­zinc(II)]

✍ Scribed by Ali, Hapipah ;Mohammad, Mazliza ;Yusof, M. Sukeri M. ;Yamin, Bohari M.

Publisher
International Union of Crystallography
Year
2003
Tongue
English
Weight
328 KB
Volume
60
Category
Article
ISSN
1600-5368

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📜 SIMILAR VOLUMES

Bis{2′-[1-(2-hydroxy­phenyl)­ethyl­idene
Bis{2′-[1-(2-hydroxy­phenyl)­ethyl­idene]­benzohydr­azido}bis­(pyridine-κN)­zinc(II)
✍ Ali, Hapipah ;Khamis, Nur Ashikin ;Basirun, W. Jefri ;Yamin, Bohari M. 📂 Article 📅 2004 🏛 International Union of Crystallography 🌐 English ⚖ 292 KB

In the centrosymmetric title compound, [Zn(C 15 H 13 N 2 O 2 ) 2 -(C 5 H 5 N) 2 ], the Zn atom is chelated by the O and N atoms of two bidentate ligands. The coordination geometry of the central Zn atom is octahedral. The crystal packing is stabilized by intermolecular CÐHÁ Á ÁO interactions.

Bis{2′-[1-(2-hydroxy-5-chloro­phenyl)­et
Bis{2′-[1-(2-hydroxy-5-chloro­phenyl)­ethyl­idene]­benzohydr­azido-κ2O,N2′}bis­(pyridine-κN)­zinc(II)
✍ Ali, Hapipah ;Khamis, Nur Ashikin ;Yamin, Bohari. M. 📂 Article 📅 2004 🏛 International Union of Crystallography 🌐 English ⚖ 429 KB

The title compound, [Zn(C 15 H 13 ClN 2 O 2 ) 2 (C 5 H 5 N) 2 ], is a centrosymmetric monomer with octahedral geometry about the Zn atom. The molecule is stabilized by intermolecular CÐ HÁ Á ÁO and CÐHÁ Á ÁCl interactions, so forming a threedimensional network.