Single-crystal X-ray study T = 150 K Mean '(C±C) = 0.005 A Ê R factor = 0.031 wR factor = 0.080 Data-to-parameter ratio = 17.4 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.
Dichloro{2,2′-thiobis[(4S)-4-isopropyl-1,3-oxazolinylphenyl]}zinc(II)
✍ Scribed by Kooijman, Huub ;Spek, Anthony L. ;Zondervan, Charon ;Feringa, Ben L.
- Publisher
- International Union of Crystallography
- Year
- 2002
- Tongue
- English
- Weight
- 227 KB
- Volume
- 58
- Category
- Article
- ISSN
- 1600-5368
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Single-crystal X-ray study T = 301 K Mean '(C±C) = 0.008 A Ê R factor = 0.025 wR factor = 0.060 Data-to-parameter ratio = 18.7 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.
In the title compound, C 21 H 19 N 5 , the pyridyl groups and the benzene ring lie in a propeller arrangement around the central 1,2,4-triazole ring, minimizing the steric effects among these rings. ## Experimental Compound (I) was synthesized by the reaction of equivalent amounts of p-isopropylp
The central Zn atom in the structure of the title compound, [ZnCl 2 (C 4 H 10 S 2 )], exhibits a distorted tetrahedral geometry and is coordinated by two Cl and two S atoms, with ZnÐCl distances of 2.203 (2) and 2.212 (2) A Ê , and ZnÐS distances of 2.390 (2) and 2.459 (2) A Ê . The angles ClÐZnÐCl