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The cocrystal {4,4′-dimethoxy-2,2′-[propane-1,2-diylbis(nitrilomethylidyne)]diphenolato}methanol(pyridine)manganese(III) hexafluoridophosphate–{4,4′-dimethoxy-2,2′-[ethane-1,2-diylbis(nitrilomethylidyne)]diphenolato}methanol(pyridine)manganese(III) hexafluoridophosphate (1/1)

✍ Scribed by Habibi, Mohammad Hossein ;Askari, Elham ;Chantrapromma, Suchada ;Fun, Hoong-Kun

Publisher: International Union of Crystallography
Year: 2007
Tongue: English
Weight: 746 KB
Volume: 63
Category: Article
ISSN: 1600-5368
DOI: 10.1107/s1600536807053883

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✦ Synopsis

The cocrystal {4,4 0 0 0 -dimethoxy-2,2 0 0 0 -[propane-1,2-diylbis(nitrilomethylidyne)]-diphenolato}methanol(pyridine)manganese(III) hexafluoridophosphate-{4,4 0 0 0dimethoxy-2,2 0 0 0 -[ethane-1,2-diylbis-(nitrilomethylidyne)]diphenolato}methanol(pyridine)manganese(III) hexafluoridophosphate (1/1

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μ-Oxido-bis({4,4′-dibromo-2,2′-[ethane-1

μ-Oxido-bis({4,4′-dibromo-2,2′-[ethane-1,2-diylbis(nitrilomethylidyne)]diphenolato}manganese(III))

✍ Liu, Ying ;Dou, Jianmin ;Niu, Meiju ;Zhang, Xianxi 📂 Article 📅 2007 🏛 International Union of Crystallography 🌐 English ⚖ 294 KB

The title compound, [Mn~2~(C~16~H~12~Br~2~N~2~O~2~)~2~O], is an unusual dinuclear manganese(III) complex. Each Mn^III^ ion has a distorted square-pyramidal coordination geometry. In the basal plane, the Mn atom is coordinated by two N atoms and two O atoms of the Schiff base ligand. The apical posit