The title compound, [Mn~2~(C~16~H~12~Br~2~N~2~O~2~)~2~O], is an unusual dinuclear manganese(III) complex. Each Mn^III^ ion has a distorted square-pyramidal coordination geometry. In the basal plane, the Mn atom is coordinated by two N atoms and two O atoms of the Schiff base ligand. The apical posit
Di-μ-oxido-bis({2,2′-[propane-1,3-diylbis(nitrilomethylidyne)]diphenolato}vanadium(IV)) dimethylformamide disolvate
✍ Scribed by Liu, Ying ;Dou, Jianmin ;Niu, Meiju ;Zhang, Xianxi
- Publisher
- International Union of Crystallography
- Year
- 2007
- Tongue
- English
- Weight
- 315 KB
- Volume
- 63
- Category
- Article
- ISSN
- 1600-5368
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✦ Synopsis
In the title compound, [V~2~(C~17~H~17~N~2~O~2~)~2~O~2~]·2C~3~H~7~NO, each V atom is chelated by a Schiff base ligand via two N and two O atoms. The two octahedrally coordinated V atoms are linked by two bridging oxide ligands to give a centrosymmetric dimer.
📜 SIMILAR VOLUMES
The title compound, [Co 3 , is an acetate-and phenolate-bridged trinuclear cobalt(II) complex. The central Co atom, lying on an inversion centre, is in an octahedral geometry. Each terminal Co atom is in a squarepyramidal geometry.
Di-l-acetato-bis[l-2-hydroxy-N,N 0 0 0 -bis(2-oxidobenzyl)propane-1,3-diamine]bis(N,N 0 0 0 -dimethylformamide)trinickel(II) N,N 0 0 0 -dimethylformamide disolvate
The title compound, [Sn 4 (CH 3 ) 8 (C 6 H 5 N 2 O 2 ) 4 O 2 ]Á6H 2 O, is a hydrated cluster containing four Sn atoms, built up by inversion symmetry around the central Sn 2 O 2 ring. The Snatom coordination geometry might be regarded as very distorted SnO 3 C 2 trigonal-bipyramidal or possibly as g