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Di-μ2-acetato-bis{μ2-1,1′-[propane-1,3-diylbis(nitrilomethylidyne)]di-2-naphtholato}tricobalt(II)

✍ Scribed by Diao, Yun-Peng ;Huang, Shan-Shan ;Zhang, Hou-Li ;Deng, Sa ;Liu, Ke-Xin

Publisher
International Union of Crystallography
Year
2007
Tongue
English
Weight
776 KB
Volume
63
Category
Article
ISSN
1600-5368

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✦ Synopsis

The title compound, [Co 3

, is an acetate-and phenolate-bridged trinuclear cobalt(II) complex. The central Co atom, lying on an inversion centre, is in an octahedral geometry. Each terminal Co atom is in a squarepyramidal geometry.

📜 SIMILAR VOLUMES

Di-μ-oxido-bis({2,2′-[propane-1,3-diylbi
Di-μ-oxido-bis({2,2′-[propane-1,3-diylbis(nitrilomethylidyne)]diphenolato}vanadium(IV)) dimethylformamide disolvate
✍ Liu, Ying ;Dou, Jianmin ;Niu, Meiju ;Zhang, Xianxi 📂 Article 📅 2007 🏛 International Union of Crystallography 🌐 English ⚖ 315 KB

In the title compound, [V~2~(C~17~H~17~N~2~O~2~)~2~O~2~]·2C~3~H~7~NO, each V atom is chelated by a Schiff base ligand __via__ two N and two O atoms. The two octahedrally coordinated V atoms are linked by two bridging oxide ligands to give a centrosymmetric dimer.