{1,1′-[Propane-1,3-diylbis(nitrilomethylidyne)]di-2-naphtholato}iron(II)
✍ Scribed by Zhao, Bin ;Sun, Yu-Xi
- Publisher
- International Union of Crystallography
- Year
- 2005
- Tongue
- English
- Weight
- 208 KB
- Volume
- 61
- Category
- Article
- ISSN
- 1600-5368
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📜 SIMILAR VOLUMES
The title compound, [Co 3 , is an acetate-and phenolate-bridged trinuclear cobalt(II) complex. The central Co atom, lying on an inversion centre, is in an octahedral geometry. Each terminal Co atom is in a squarepyramidal geometry.
The structure of the title compound, C 19 H 22 N 2 O 2 , shows two intramolecular O-HÁ Á ÁN hydrogen-bonding interactions. The packing is stabilized through van der Waals contacts and two C-HÁ Á Á interactions.
In the title compound, [Zn(C~17~H~16~N~2~O~2~)(H~2~O)], the Zn^II^ atom has a distorted pentacoordinate square-pyramidal geometry. A mirror plane passes through the Zn^II^ atom, the central C atom of the propyl group and the O atom of the coordinated water molecule. The two planar Schiff base groups