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Aqua­{2,2′-[propane-1,3-diylbis(nitrilo­methyl­idyne)]diphenolato}zinc(II)

✍ Scribed by Odoko, Mamiko ;Tsuchida, Natsuko ;Okabe, Nobuo

Publisher
International Union of Crystallography
Year
2006
Tongue
English
Weight
202 KB
Volume
62
Category
Article
ISSN
1600-5368

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✦ Synopsis

In the title compound, [Zn(C~17~H~16~N~2~O~2~)(H~2~O)], the Zn^II^ atom has a distorted pentacoordinate square-pyramidal geometry. A mirror plane passes through the Zn^II^ atom, the central C atom of the propyl group and the O atom of the coordinated water molecule. The two planar Schiff base groups make a dihedral angle of 39.49 (6)°. The crystal packing is stabilized by weak intermolecular interactions via the coordinated water molecule.

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{6,6 0 0 0 -Dimethoxy-2,2 0 0 0 -[ethane-1,2-diylbis-(nitrilomethylidyne)]diphenolato}(ethanol)dioxouranium(VI) Nuray S ¸enyu ¨z, a C ¸ig ˆdem Yu ¨ksektepe, b \* Hu ¨meyra Batı, a Nezihe C ¸alıs ¸kan b and Orhan Bu ¨yu ¨kgu ¨ngo ¨rb