(η5-1-substituted-pentadienyl) (tricarbonyl)iron(+1) cations:Reactivity with malonate nucleophiles

✍ Scribed by Wlliam A. Donaldson; Muthukumar Ramaswamy

• Book ID: 104216490
• Publisher: Elsevier Science
• Year: 1988
• Tongue: French
• Weight: 249 KB
• Volume: 29
• Category: Article
• ISSN: 0040-4039
• DOI: 10.1016/s0040-4039(00)80292-0

✦ Synopsis

The title compounds react with malonate anions by attack at both the substituted and unsubstituted terminii, to afford the trans-cis substituted diene products.

(Q'-Cyclohexadienylj-and (Q5-cycloheptadienyl)iron(+ll cations are important synthetic precursors due to their regio-and stereoselective reaction with carbon and heteroatom