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(η5-1-substituted-pentadienyl) (tricarbonyl)iron(+1) cations: reactivity with alkynyl nucleophiles

✍ Scribed by William A Donaldson; Muthukumar Ramaswamy

Book ID
104229611
Publisher
Elsevier Science
Year
1989
Tongue
French
Weight
268 KB
Volume
30
Category
Article
ISSN
0040-4039

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(η5-1-substituted-pentadienyl) (tricarbo
(η5-1-substituted-pentadienyl) (tricarbonyl)iron(+1) cations:Reactivity with malonate nucleophiles
✍ Wlliam A. Donaldson; Muthukumar Ramaswamy 📂 Article 📅 1988 🏛 Elsevier Science 🌐 French ⚖ 249 KB

The title compounds react with malonate anions by attack at both the substituted and unsubstituted terminii, to afford the trans-cis substituted diene products. (Q'-Cyclohexadienylj-and (Q5-cycloheptadienyl)iron(+ll cations are important synthetic precursors due to their regio-and stereoselective r