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Synthesis and reactivity of (tricarbonyl)-(η5-2-methylpentadienyl)iron(+1) cation

✍ Scribed by William A. Donaldson


Book ID
103224814
Publisher
Elsevier Science
Year
1990
Tongue
English
Weight
556 KB
Volume
395
Category
Article
ISSN
0022-328X

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(η5-1-substituted-pentadienyl) (tricarbo
✍ Wlliam A. Donaldson; Muthukumar Ramaswamy 📂 Article 📅 1988 🏛 Elsevier Science 🌐 French ⚖ 249 KB

The title compounds react with malonate anions by attack at both the substituted and unsubstituted terminii, to afford the trans-cis substituted diene products. (Q'-Cyclohexadienylj-and (Q5-cycloheptadienyl)iron(+ll cations are important synthetic precursors due to their regio-and stereoselective r