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Synthesis and reactivity of tricarbonyl(η5-4-triethylsilyl-1methylpentadienyl) iron(+1) cation

✍ Scribed by William A. Donaldson; Peter T. Bell; Myung-Jong Jin


Book ID
103226637
Publisher
Elsevier Science
Year
1992
Tongue
English
Weight
590 KB
Volume
441
Category
Article
ISSN
0022-328X

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(η5-1-substituted-pentadienyl) (tricarbo
✍ Wlliam A. Donaldson; Muthukumar Ramaswamy 📂 Article 📅 1988 🏛 Elsevier Science 🌐 French ⚖ 249 KB

The title compounds react with malonate anions by attack at both the substituted and unsubstituted terminii, to afford the trans-cis substituted diene products. (Q'-Cyclohexadienylj-and (Q5-cycloheptadienyl)iron(+ll cations are important synthetic precursors due to their regio-and stereoselective r