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β-Bi 4 (P 2 Se 6 ) 3 : A New Ternary Selenophosphate Obtained in a P 2 Se 5 Flux

✍ Scribed by Aitken, Jennifer A.; Brown, Shannon; Chondroudis, Konstantinos; Jobic, Stéphane; Brec, Raymond; Kanatzidis, Mercouri G.

Book ID
126979172
Publisher
American Chemical Society
Year
1999
Tongue
English
Weight
172 KB
Volume
38
Category
Article
ISSN
0020-1669

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Synthesis of the One-dimensional Compoun
Synthesis of the One-dimensional Compound (Ph4P)[In(P2Se6)] in a Ph4P+-Containing Selenophosphate Flux, and Structure of [In(P2Se6)2]5– – a Discrete Molecular Fragment of the [In(P2Se6)]nn– Chain
✍ Konstantinos Chondroudis; Debojit Chakrabarty; Enos A. Axtell; Mercouri G. Kanat 📂 Article 📅 1998 🏛 John Wiley and Sons 🌐 German ⚖ 137 KB 👁 2 views

The reaction of one equivalent of In with a molten flux of (Ph 4 P) 2 Se 5 and P 2 Se 5 (1 : 2), at 250 °C gave the (Ph 4 P)[In(P 2 Se 6 )] (I). Stoichiometric elemental synthesis at 750 °C produced the Cs 5 In(P 2 Se 6 ) 2 (II). The thin, yellow crystals of (I), and the irregular, dark orange cryst

K4In2(PSe5)2(P2Se6) and Rb3Sn(PSe5)(P2Se
K4In2(PSe5)2(P2Se6) and Rb3Sn(PSe5)(P2Se6): One-Dimensional Compounds with Mixed Selenophosphate Anions
✍ Konstantinos Chondroudis; Mercouri G. Kanatzidis 📂 Article 📅 1998 🏛 Elsevier Science 🌐 English ⚖ 722 KB

Cc (9) with a‫؍‬ 11.1564(1) A s , b‫)1(1778.22؍‬ A s , c‫)2(5256.21؍‬ A s , ‫,°)1(930.901؍‬ Z‫,4؍‬ and R/R w ‫.%4.4/1.4؍‬ The one-dimensional structure features [In 2 (PSe 5 ) 2 (P 2 Se 6 )] 4n؊ n chains that consist of In 2 (PSe 5 ) 2 dimers. These dimers are then bridged along the a-axis by tetra