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ChemInform Abstract: β-Bi4(P2Se6)3: A New Ternary Selenophosphate Obtained in a P2Se5 Flux.

✍ Scribed by Jennifer A. Aitken; Shannon Brown; Konstantinos Chondroudis; Stephane Jobic; Raymond Brec; Mercouri G. Kanatzidis


Publisher
John Wiley and Sons
Year
2010
Weight
35 KB
Volume
30
Category
Article
ISSN
0931-7597

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The reaction of one equivalent of In with a molten flux of (Ph 4 P) 2 Se 5 and P 2 Se 5 (1 : 2), at 250 °C gave the (Ph 4 P)[In(P 2 Se 6 )] (I). Stoichiometric elemental synthesis at 750 °C produced the Cs 5 In(P 2 Se 6 ) 2 (II). The thin, yellow crystals of (I), and the irregular, dark orange cryst