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ChemInform Abstract: Synthesis of the One-Dimensional Compound (Ph4P)[In(P2Se6)] in a Ph4P+-Containing Selenophosphate Flux, and Structure of [In(P2Se6)2]5- — A Discrete Molecular Fragment of the [In(P2Se6)]nn- Chain.

✍ Scribed by K. CHONDROUDIS; D. CHAKRABARTY; E. A. AXTELL; M. G. KANATZIDIS

Publisher
John Wiley and Sons
Year
2010
Weight
39 KB
Volume
29
Category
Article
ISSN
0931-7597

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Synthesis of the One-dimensional Compoun
Synthesis of the One-dimensional Compound (Ph4P)[In(P2Se6)] in a Ph4P+-Containing Selenophosphate Flux, and Structure of [In(P2Se6)2]5– – a Discrete Molecular Fragment of the [In(P2Se6)]nn– Chain
✍ Konstantinos Chondroudis; Debojit Chakrabarty; Enos A. Axtell; Mercouri G. Kanat 📂 Article 📅 1998 🏛 John Wiley and Sons 🌐 German ⚖ 137 KB 👁 2 views

The reaction of one equivalent of In with a molten flux of (Ph 4 P) 2 Se 5 and P 2 Se 5 (1 : 2), at 250 °C gave the (Ph 4 P)[In(P 2 Se 6 )] (I). Stoichiometric elemental synthesis at 750 °C produced the Cs 5 In(P 2 Se 6 ) 2 (II). The thin, yellow crystals of (I), and the irregular, dark orange cryst

ChemInform Abstract: Synthesis, Structur
ChemInform Abstract: Synthesis, Structure, and Properties of Cs4Th4P4Se26: A Quaternary Thorium Selenophosphate Containing the (P2Se9)6- Anion.
✍ Paula M. Briggs Piccoli; Kent D. Abney; Jon D. Schoonover; Peter K. Dorhout 📂 Article 📅 2010 🏛 John Wiley and Sons ⚖ 33 KB

## Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a “Full Text” option. The original article is trackable v

Two New Carbon-Free Indium(III) Asymmetr
Two New Carbon-Free Indium(III) Asymmetric Chelates – Synthesis and X-ray Crystal Structures of [In{Ph2P(O)NP(S)Ph2-O,S}3]·3/4 C6H6 and [InCl{Ph2P(S)NP(Se)Ph2-S,Se}2]
✍ Raymundo Cea-Olivares; Rubén A. Toscano; Simón Hernández-Ortega; Josef Novosad; 📂 Article 📅 1999 🏛 John Wiley and Sons 🌐 English ⚖ 253 KB 👁 2 views

The ligands [Ph 2 (S)PNHP(X)Ph 2 ] -(X = O, Se) react with InCl 3 coordination geometry in 2 resembles that observed in the three analogous tris-chelates incorporating the corres-in a 3:1 ratio to give a tris-chelate [In{Ph 2 P(O)NP(S)Ph 2 -O,S} 3 ]•0.75 C 6 H 6 (2) and the unexpected pentacoordinat