Oxidative Coupling of the Selenolate Functions in (C6H5)3PC(Se)P(C6H5)3: Crystal Structure of {[(C6H5)3P]2CSe}Fe2OCl·4CH2Cl2 Containing a Linear FeOFe Axis
✍ Scribed by Prof. Dr. Hubert Schmidbaur; Christian E. Zybill; Dr. Dietmar Neugebauer
- Publisher
- John Wiley and Sons
- Year
- 1983
- Tongue
- English
- Weight
- 202 KB
- Volume
- 22
- Category
- Article
- ISSN
- 0044-8249
No coin nor oath required. For personal study only.
✦ Synopsis
Abstract
The complete manuscript of this communication appears in: Angew. Chem. Suppl. 1983, 169. DOI:10.1002/anie.198301690
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The crystallographic dataC3] and the molecular dimensions of ( 4 ) and ( ) are almost identical. We thus have one of those rare cases in which analyses and spectraL4] are more significant in identifying the compounds than structure determination. The most important structural characteristic of ( 4 )
Reaction of elemental antimony with sulfur under mild hydrothermal conditions yielded different polysulfidoclusters of antimony. These were isolated as tetraphenylphosphonium salts [P(C 6 H 5 ) 4 ] 3 Sb 3 S 25 and [P(C 6 H 5 ) 4 ] 2 Sb 2 S 15 2(C 3 N 2 H 6 ) and their crystal structures were determi