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Zirconium Complexes Containing Bidentate Pyrrole Ligands: Synthesis, Structural Characterization, and Ethylene Polymerization

✍ Scribed by Huang, Jui-Hsien; Chi, Liang-Sheng; Yu, Ru-Ching; Jiang, George J.; Yang, Wei-Ta; Lee, Gene-Hsiang; Peng, Shie-Ming


Book ID
126171690
Publisher
American Chemical Society
Year
2001
Tongue
English
Weight
64 KB
Volume
20
Category
Article
ISSN
0276-7333

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The synthesis of chelating diamidodibenzyl complexes of the type Zr( 2)] is described. The fluxionality of these complexes in solution has been studied by means of variable-temperature NMR. In the presence of one equivalent of a suitable alkyl abstractor, these compounds proved to behave as moderate