Synthesis and molecular structures of zirconium complexes that contain bidentate amido ligands
β Scribed by Matthew D. Lococo; Han Lee; Richard F. Jordan
- Book ID
- 103838430
- Publisher
- Elsevier Science
- Year
- 2009
- Tongue
- English
- Weight
- 532 KB
- Volume
- 920
- Category
- Article
- ISSN
- 0022-2860
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The synthesis of chelating diamidodibenzyl complexes of the type Zr( 2)] is described. The fluxionality of these complexes in solution has been studied by means of variable-temperature NMR. In the presence of one equivalent of a suitable alkyl abstractor, these compounds proved to behave as moderate
Neutral oxorhenium(V) complexes with dithioether ligands of the general formula [ReOX3(RS[CHz]2SR)], X = C1, Br, R = nBu, Et, Bzl were synthesized. Ammonium perrhenate reacts in concentrated hydrochloric acid with dithiaalkanes (RS[CH2I2SR, R = nBu, Et, Bzl) dissolved in glacial acetic acid to give