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Synthesis, characterization and crystal structures of tetrairon ethanedithiolate complexes containing bridging bidentate phosphine ligands

✍ Scribed by Xu-Feng Liu; Zhong-Qing Jiang; Zhi-Jian Jia


Book ID
113856753
Publisher
Elsevier Science
Year
2012
Tongue
English
Weight
838 KB
Volume
33
Category
Article
ISSN
0277-5387

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Synthesis and Structural Characterizatio
✍ Reisgys, Martina ;Spies, Hartmut ;Johannesn, Bernd ;Pietzsch, Hans-Jergen ;Leibn πŸ“‚ Article πŸ“… 1997 πŸ› Wiley (John Wiley & Sons) 🌐 English βš– 493 KB πŸ‘ 1 views

Neutral oxorhenium(V) complexes with dithioether ligands of the general formula [ReOX3(RS[CHz]2SR)], X = C1, Br, R = nBu, Et, Bzl were synthesized. Ammonium perrhenate reacts in concentrated hydrochloric acid with dithiaalkanes (RS[CH2I2SR, R = nBu, Et, Bzl) dissolved in glacial acetic acid to give