𝔖 Bobbio Scriptorium
✦   LIBER   ✦

Zinc-Catalyzed Enantioselective Hydrosilylation of Imines.

✍ Scribed by Bu-Mahn Park; Soungyun Mun; Jaesook Yun

Book ID
101997518
Publisher
John Wiley and Sons
Year
2006
Weight
21 KB
Volume
37
Category
Article
ISSN
0931-7597

No coin nor oath required. For personal study only.

✦ Synopsis

Abstract

ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 200 leading journals. To access a ChemInform Abstract, please click on HTML or PDF.

πŸ“œ SIMILAR VOLUMES

Zinc-Catalyzed Enantioselective Hydrosil
Zinc-Catalyzed Enantioselective Hydrosilylation of Imines
✍ Bu-Mahn Park; Soungyun Mun; Jaesook Yun πŸ“‚ Article πŸ“… 2006 πŸ› John Wiley and Sons 🌐 English βš– 82 KB πŸ‘ 1 views

## Abstract The highly enantioselective reduction of imines is achieved by employing chiral Zn/diamine catalysts. This new catalytic protocol offers attractive features such as use of a non‐precious metal and an inexpensive silane, easy modification of chiral diamine ligands and provides ready acce

Convenient Enantioselective Hydrosilylat
Convenient Enantioselective Hydrosilylation of Ketones Catalyzed by Zinc-Macrocyclic Oligoamine Complexes
✍ Jadwiga Gajewy; Marcin Kwit; Jacek GawroΕ„ski πŸ“‚ Article πŸ“… 2009 πŸ› John Wiley and Sons 🌐 English βš– 303 KB πŸ‘ 2 views

## Abstract magnified image Chiral macrocyclic tetra‐ and hexamine macrocycles derived from __trans__‐1,2‐diaminocyclohexane (DACH) in complexes with diethylzinc efficiently catalyze the asymmetric hydrosilylation of aryl alkyl ketones with enantiomeric excess of the product up to 89%. The cyclic