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Zinc-Catalyzed Enantioselective Hydrosilylation of Imines

โœ Scribed by Bu-Mahn Park; Soungyun Mun; Jaesook Yun

Book ID
101422699
Publisher
John Wiley and Sons
Year
2006
Tongue
English
Weight
82 KB
Volume
348
Category
Article
ISSN
1615-4150

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โœฆ Synopsis

Abstract

The highly enantioselective reduction of imines is achieved by employing chiral Zn/diamine catalysts. This new catalytic protocol offers attractive features such as use of a nonโ€precious metal and an inexpensive silane, easy modification of chiral diamine ligands and provides ready access to chiral amines in good yields and with excellent enantioselectivities.

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