Enantioselective Zinc-Catalyzed Hydrosilylation of Ketones using Pybox or Pybim Ligands
✍ Scribed by Dr. Kathrin Junge; Konstanze Möller; Bianca Wendt; Shoubhik Das; Dr. Dirk Gördes; Prof. Dr. Kerstin Thurow; Prof. Dr. Matthias Beller
- Book ID
- 112006441
- Publisher
- John Wiley and Sons
- Year
- 2011
- Tongue
- English
- Weight
- 407 KB
- Volume
- 7
- Category
- Article
- ISSN
- 1861-4728
No coin nor oath required. For personal study only.
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## Abstract magnified image Chiral macrocyclic tetra‐ and hexamine macrocycles derived from __trans__‐1,2‐diaminocyclohexane (DACH) in complexes with diethylzinc efficiently catalyze the asymmetric hydrosilylation of aryl alkyl ketones with enantiomeric excess of the product up to 89%. The cyclic