Zero-field splitting in the triplet ground state of nickelocene
✍ Scribed by R. Prins; J.D.W. van Voorst; C.J. Schinkel
- Book ID
- 107731196
- Publisher
- Elsevier Science
- Year
- 1967
- Tongue
- English
- Weight
- 187 KB
- Volume
- 1
- Category
- Article
- ISSN
- 0009-2614
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📜 SIMILAR VOLUMES
Zero-field-splitting parameters D and E for the fullerene GO in its Jahn-Teller distorted triplet state were calculated and compared to recent experimental results. The E value vanishes due to symmetry, while we obtained a non-zero k) value of D = -0.009 cm-' in the Ds distorted lowest triplet state
## Rcceivlzd 30 bloy 1975 The clcctronic spectra of the two title compounds arc computed in the CND0j.S app:oximation. The zero-field splittings arc dclived. They ;~rc govcrncd by the spin-orbit coupling with a close lying singlet State.
The loNest evcrted rrlplet sutc of acetone was mvestrgatcd with 3 pulsed dye-laser-cqulpped ODLIR spccfromctcr. The zero-field sph!rrng parametcrsD = 4 8 CHz and E = 1.3 GHz compare favourably with a recent ab IIUIIO cslculatlon on bent lrlplet formaldehyde. The kmelx data mdlcale a surprlungly smal