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The lowest excited triplet state of acetone: zero-field splitting and kinetics

✍ Scribed by M. Gehrtz; Chr. Bräuchle; J. Voitländer

Publisher
Elsevier Science
Year
1982
Tongue
English
Weight
347 KB
Volume
91
Category
Article
ISSN
0009-2614

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✦ Synopsis

The loNest evcrted rrlplet sutc of acetone was mvestrgatcd with 3 pulsed dye-laser-cqulpped ODLIR spccfromctcr. The zero-field sph!rrng parametcrsD = 4 8 CHz and E = 1.3 GHz compare favourably with a recent ab IIUIIO cslculatlon on bent lrlplet formaldehyde. The kmelx data mdlcale a surprlungly small ro1a11on of the magneticau~s system.

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