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Zero-field-splitting in the lowest triplet state of C60

✍ Scribed by P.R. Surján; K. Németh; M. Bennati; A. Grupp; M. Mehring

Publisher
Elsevier Science
Year
1996
Tongue
English
Weight
387 KB
Volume
251
Category
Article
ISSN
0009-2614

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✦ Synopsis

Zero-field-splitting parameters D and E for the fullerene GO in its Jahn-Teller distorted triplet state were calculated and compared to recent experimental results. The E value vanishes due to symmetry, while we obtained a non-zero k) value of D = -0.009 cm-' in the Ds distorted lowest triplet state. The absolute value of D is in good agreement with exberimental data, which suggests that the sign of D is negative.

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