Zero-field splittings in aromatic triplet states
β Scribed by Colin Thomson
- Publisher
- Springer
- Year
- 1968
- Tongue
- English
- Weight
- 123 KB
- Volume
- 11
- Category
- Article
- ISSN
- 1432-2234
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π SIMILAR VOLUMES
A linear relationship is found between the ZFS parameter D and the energy of the lowest tripIet state. Experimental and theoretical values. when plott,ed. give straight lines with similar slopes.
## Abstract The ESR spectra of some aromatic chargeβtransfer complexes in the lowest excited triplet states were measured. From the extracted zeroβfieldβsplitting parameters it was found that in each case the lowest excited triplet state was localized on the donor, with a variable contribution of c
Zero-field-splitting parameters D and E for the fullerene GO in its Jahn-Teller distorted triplet state were calculated and compared to recent experimental results. The E value vanishes due to symmetry, while we obtained a non-zero k) value of D = -0.009 cm-' in the Ds distorted lowest triplet state