A linear relationship is found between the ZFS parameter D and the energy of the lowest tripIet state. Experimental and theoretical values. when plott,ed. give straight lines with similar slopes.
Zero-field splitting in phosphorescent triplet states of aromatic hydrocarbons IV. Phenyl naphthalenes
โ Scribed by M. K. Orloff; J. S. Brinen
- Publisher
- John Wiley and Sons
- Year
- 1969
- Tongue
- English
- Weight
- 322 KB
- Volume
- 3
- Category
- Article
- ISSN
- 0020-7608
No coin nor oath required. For personal study only.
๐ SIMILAR VOLUMES
Recently several investigators reported opti-aZ detection of ESR transitions in phosphoresent triplet states of various molecules [l-3]. he experiments were done by sweeping the magetic field at fixed microwave frequency. In con-;ast with the normal ESR detection method. the Jsorption of microwave p
The zero fickl transition energies in the phosphorwcent triplet state of neat SO 2 arc discctly mctsurcd by opticlL detedtion at 1.4"K, leading to LDI = 0.275 cm-' and LEI = 0.01575 cm-' for the usual spin hamiltonian parameters. Two spin states are found to be active in the phosphorescence with th