✦ LIBER ✦

Optical detection of the zero field splittings in the phosphorescent triplet state of neat SO2 crystals

✍ Scribed by D.S. Tinti

Publisher: Elsevier Science
Year: 1971
Tongue: English
Weight: 396 KB
Volume: 12
Category: Article
ISSN: 0009-2614
DOI: 10.1016/0009-2614(71)80642-5

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✦ Synopsis

The zero fickl transition energies in the phosphorwcent triplet state of neat SO 2 arc discctly mctsurcd by opticlL detedtion at 1.4"K, leading to LDI = 0.275 cm-' and LEI = 0.01575 cm-' for the usual spin hamiltonian parameters.

Two spin states are found to be active in the phosphorescence with the dominant spin state having a IKetime of 2 msec.

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