The zero fickl transition energies in the phosphorwcent triplet state of neat SO 2 arc discctly mctsurcd by opticlL detedtion at 1.4"K, leading to LDI = 0.275 cm-' and LEI = 0.01575 cm-' for the usual spin hamiltonian parameters. Two spin states are found to be active in the phosphorescence with th
The phosphorescent state of γ-thiopyrones: Optically-resolved zero-field splittings
✍ Scribed by M.R. Taherian; A.H. Maki
- Publisher
- Elsevier Science
- Year
- 1983
- Tongue
- English
- Weight
- 627 KB
- Volume
- 96
- Category
- Article
- ISSN
- 0009-2614
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✦ Synopsis
The phosphorescence spectra, ODMR, and triplet sublc~el kinetics are reported for the thioketoncs, 4H-p-ran4thionc (Pr) and 2,6dimethyl4H-pyran4thione (DMPT). Extremely large ZFS parameters. D = -24, and -28 cm-'. arc ass@ntld to two distinct trap sites of PT in Jz-pentnne and D = -24 cm-1 for the major site of DhlPT in n-hexme.
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