The title compound, C 15 H 17 NO 2 , was prepared by the basecatalyzed reaction of 4-methoxybenzaldehyde with 1-azabicyclo[2.2.2]octan-3-one. The configuration about the olefinic bond connecting the methoxyphenyl and 1-azabicylo[2.2.2]octan-3-one moieties is Z.
(Z)-3-(4-Methoxybenzylidene)-2-methylisoindolin-1-one
✍ Scribed by Warzecha, Klaus-Dieter ;Neudörfl, Jörg M. ;Griesbeck, Axel G.
- Publisher
- International Union of Crystallography
- Year
- 2005
- Tongue
- English
- Weight
- 193 KB
- Volume
- 61
- Category
- Article
- ISSN
- 1600-5368
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✦ Synopsis
The title compound, C 17 H 15 NO 2 , consists of two planar subunits, viz. a lactam and a 4-methoxybenzyl moiety. The double bond connecting the sub-units has a Z configuration.
📜 SIMILAR VOLUMES
The title molecule, C 20 H 20 N 2 O 2 S, exits in the Z form and the five-membered imidazole ring and the benzene ring of the 4methoxybenzylidene moiety are almost coplanar. Short intramolecular contacts [CÁ Á ÁS = 3.138 (4) A ˚and CÁ Á ÁN = 3.060 (4) A ˚] indicate the presence of weak C-HÁ Á ÁS and
The title compound, C 15 H 17 NO 2 , was prepared by basecatalyzed reaction of 2-methoxybenzaldehyde with 1-azabicyclo[2.2.2]octan-3-one. The configuration about the olefinic bond connecting the methoxyphenyl and 1-azabicylo[2.2.2]octan-3-one moieties is Z.
The title compound, C~23~H~12~N~4~O, has potential application in non-linear optics; it has a chiral crystal structure despite the lack of a stereogenic centre. The crystal structure involves two intermolecular C—H...N hydrogen bonds.
The title compound, C 21 H 22 O 2 , has the exocyclic C C double bond in an E configuration. The isopropyl group is attached in an axial position to the cyclohexenone ring.