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(Z)-2-(2-Methoxy­benzyl­idene)-1-aza­bicyclo­[2.2.2]octan-3-one

✍ Scribed by Sonar, Vijayakumar N. ;Parkin, Sean ;Crooks, Peter A.

Publisher
International Union of Crystallography
Year
2006
Tongue
English
Weight
174 KB
Volume
62
Category
Article
ISSN
1600-5368

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✦ Synopsis

The title compound, C 15 H 17 NO 2 , was prepared by basecatalyzed reaction of 2-methoxybenzaldehyde with 1-azabicyclo[2.2.2]octan-3-one. The configuration about the olefinic bond connecting the methoxyphenyl and 1-azabicylo[2.2.2]octan-3-one moieties is Z.

📜 SIMILAR VOLUMES

(Z)-2-(4-Methoxy­benzyl­idene)-1-aza­bic
(Z)-2-(4-Methoxy­benzyl­idene)-1-aza­bicyclo­[2.2.2]octan-3-one
✍ Sonar, Vijayakumar N. ;Parkin, Sean ;Crooks, Peter A. 📂 Article 📅 2006 🏛 International Union of Crystallography 🌐 English ⚖ 98 KB

The title compound, C 15 H 17 NO 2 , was prepared by the basecatalyzed reaction of 4-methoxybenzaldehyde with 1-azabicyclo[2.2.2]octan-3-one. The configuration about the olefinic bond connecting the methoxyphenyl and 1-azabicylo[2.2.2]octan-3-one moieties is Z.

(3Z)-2-Benzyl-3-benzyl­idene-6-phenyl-2-
(3Z)-2-Benzyl-3-benzyl­idene-6-phenyl-2-aza­bicyclo­[2.2.2]octan-5-one
✍ Sridhar, B. ;Ravikumar, K. ;Mahesh, M. ;Reddy, V. V. Narayana 📂 Article 📅 2007 🏛 International Union of Crystallography 🌐 English ⚖ 223 KB

In the title compound, C~27~H~25~NO, all three rings in the azabicyclo[2.2.2]octane unit adopt a boat conformation. An intermolecular C—H...O interaction forms a characteristic __R__ ~2~ ^2^(14) motif dimer in the crystal packing.