In the title compound, C 19 H 19 N 3 O, the five-membered imidazolone ring is essentially planar, and the packing of the molecules in the crystal structure is mainly due to intermolecular N-HÁ Á ÁO hydrogen-bonding interactions, which link the molecules into chains.
4-Isopropyl-2-(4-methoxybenzylidene)-3,4-dihydronaphthalen-1(2H)-one
✍ Scribed by Al Houari, Ghali ;Kerbal, Abdelali ;El Bali, Brahim ;Bolte, Michael
- Publisher
- International Union of Crystallography
- Year
- 2005
- Tongue
- English
- Weight
- 93 KB
- Volume
- 61
- Category
- Article
- ISSN
- 1600-5368
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✦ Synopsis
The title compound, C 21 H 22 O 2 , has the exocyclic C C double bond in an E configuration. The isopropyl group is attached in an axial position to the cyclohexenone ring.
📜 SIMILAR VOLUMES
The crystal structure of the title compound, C 19 H 19 N 3 O 2 , shows the molecule to be essentially planar with the exception of the terminal phenyl group. Molecules are associated via intermolecular C-HÁ Á ÁO hydrogen bonds.
In the crystal structure of the title compound, C 19 H 19 N 3 O 3 , the benzene ring substituted by hydroxy and methoxy groups is essentially coplanar with the pyrazoline ring [dihedral angle = 12.9 (2) ], whereas the phenyl ring bonded directly to the pyrazoline ring forms a dihedral angle of 50.4
The title compound, C 17 H 15 NO 2 , consists of two planar subunits, viz. a lactam and a 4-methoxybenzyl moiety. The double bond connecting the sub-units has a Z configuration.
Single-crystal X-ray study T = 295 K Mean '(C±C) = 0.004 A Ê R factor = 0.052 wR factor = 0.174 Data-to-parameter ratio = 14.0 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.