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X-ray Absorption Spectroscopic Studies of Chromium Nitroso Complexes. Crystal and Molecular Structure of (Ph 4 P) 3 [Cr(NO)(NCS) 5 ]·2.4(CH 3 ) 2 CO

✍ Scribed by Levina, Aviva; Turner, Peter; Lay, Peter A.


Book ID
126023734
Publisher
American Chemical Society
Year
2003
Tongue
English
Weight
147 KB
Volume
42
Category
Article
ISSN
0020-1669

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The triisocyanide ligand CH3C(CH2NC)3 reacts with Cr-acterized by an X-ray structure analysis allowing a direct com-(CO),(THF) depending on the stoichiometry to give the com-parison of the bonding parameters of coordinated and nonplexes CH3C(CH2NC),[CH2NC ~ Cr(C0)5]3-, (x = 1, 2). The coordinated is