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Isothiocyanato complexes of rhenium III. Synthesis and characterization of [ReN(NCS)2(Ph3P)2] and [ReN(NCS)2(CH3CN)(Ph3P)2]. X-ray crystal structure of [ReN(NCS)2(CH3CN)(Ph3P)2]·CH3CN

✍ Scribed by Rainer Hübener; Ulrich Abram; Joachim Strähle


Publisher
Elsevier Science
Year
1994
Tongue
English
Weight
484 KB
Volume
224
Category
Article
ISSN
0020-1693

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The triisocyanide ligand CH3C(CH2NC)3 reacts with Cr-acterized by an X-ray structure analysis allowing a direct com-(CO),(THF) depending on the stoichiometry to give the com-parison of the bonding parameters of coordinated and nonplexes CH3C(CH2NC),[CH2NC ~ Cr(C0)5]3-, (x = 1, 2). The coordinated is