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Coordinatedversus Noncoordinated Isocyanides: Synthesis of Complexes CH3C(CH2NC)x[CH2NC—Cr(CO)5]3-x(x=1, 2) and Crystal Structure of CH3C(CH2NC)2[CH2NC — Cr(CO)5]

✍ Scribed by Ekkehardt Hahn, F. ;Tamm, Matthias

Publisher: Wiley (John Wiley & Sons)
Year: 1992
Tongue: English
Weight: 246 KB
Volume: 125
Category: Article
ISSN: 0009-2940
DOI: 10.1002/cber.19921250120

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✦ Synopsis

The triisocyanide ligand CH3C(CH2NC)3 reacts with Cr-acterized by an X-ray structure analysis allowing a direct com-(CO),(THF) depending on the stoichiometry to give the com-parison of the bonding parameters of coordinated and nonplexes CH3C(CH2NC),[CH2NC ~ Cr(C0)5]3-, (x = 1, 2). The coordinated isocyanide ligands in the same molecule. complex CH3C(CH2NC)2[CH2NC -Cr(CO),] has been char-

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