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Synthesis and Carbonylation of Platinum(II) Organometallic Complexes with Bis(phosphanyl) Monosulfides − Crystal Structures of [κ2P,S-{Ph2CH2P(S)Ph2}Pt(CH3)(Cl)] and [κP,μ-κS-{Ph2CH2CH2P(S)Ph2}Pt-(CH3)]2[BF4]2

✍ Scribed by Piero Mastrorilli; Cosimo F. Nobile; Gian P. Suranna; Francesco P. Fanizzi; Giuseppe Ciccarella; Ulli Englert; Qi Li


Publisher
John Wiley and Sons
Year
2004
Tongue
English
Weight
205 KB
Volume
2004
Category
Article
ISSN
1434-1948

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The Evolution of [{Ph2P(CH2)nPPh2}Pt(μ-S
✍ Rubén Mas-Ballesté; Gabriel Aullón; Paul A. Champkin; William Clegg; Claire Mégr 📂 Article 📅 2003 🏛 John Wiley and Sons 🌐 English ⚖ 304 KB

## Abstract Given the nucleophilicity of the {Pt~2~S~2~} ring, the evolution of [Pt~2~(μ‐S)~2~(P∩P)~2~] (P∩P=1,2‐bis(diphenylphosphino)ethane (dppe), 1,3‐bis(diphenylphosphino)propane (dppp)) metalloligands in the presence of the simplest electrophilic species, the proton, has been studied. Combine