Dithiolatliganden bilden rnit Ubergangsrnetallen Komplexe mannigfaltiger Strukturtypen und mit unterschiedlicher Anzahl an Metallatomen. Trotzdem ist die entsprechende Chemie von Metallen der 5. Gruppe des Periodensystems nicht sehr gut erschlossen. Wir haben kurzlich uber die Synthese der anionisch
✦ LIBER ✦
Self-Reduction of [Ph4P][Nb(SCH2CH2CH2S)3] with Formation of a Nb Complex
✍ Scribed by Dr. Kazuyuki Tatsumi; Yoitsu Sekiguchi; Michiyo Sebata; Prof. Dr. Akira Nakamura; Prof. Dr. Roger E. Cramer; Thomas Chung
- Publisher
- John Wiley and Sons
- Year
- 1989
- Tongue
- English
- Weight
- 491 KB
- Volume
- 28
- Category
- Article
- ISSN
- 0044-8249
No coin nor oath required. For personal study only.
✦ Synopsis
Some chemical reactions of the triethylammonium salts of 2 are summarized in Scheme 2.
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Selbstreduktion von [Ph4P][Nb(SCH2CH2CH2
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## Abstract Given the nucleophilicity of the {Pt~2~S~2~} ring, the evolution of [Pt~2~(μ‐S)~2~(P∩P)~2~] (P∩P=1,2‐bis(diphenylphosphino)ethane (dppe), 1,3‐bis(diphenylphosphino)propane (dppp)) metalloligands in the presence of the simplest electrophilic species, the proton, has been studied. Combine
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