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Self-Reduction of [Ph4P][Nb(SCH2CH2CH2S)3] with Formation of a Nb Complex

✍ Scribed by Dr. Kazuyuki Tatsumi; Yoitsu Sekiguchi; Michiyo Sebata; Prof. Dr. Akira Nakamura; Prof. Dr. Roger E. Cramer; Thomas Chung


Publisher
John Wiley and Sons
Year
1989
Tongue
English
Weight
491 KB
Volume
28
Category
Article
ISSN
0044-8249

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✦ Synopsis


Some chemical reactions of the triethylammonium salts of 2 are summarized in Scheme 2.


📜 SIMILAR VOLUMES


Selbstreduktion von [Ph4P][Nb(SCH2CH2CH2
✍ Dr. Kazuyuki Tatsumi; Yoitsu Sekiguchi; Michiyo Sebata; Prof. Dr. Akira Nakamura 📂 Article 📅 1989 🏛 John Wiley and Sons 🌐 English ⚖ 290 KB 👁 1 views

Dithiolatliganden bilden rnit Ubergangsrnetallen Komplexe mannigfaltiger Strukturtypen und mit unterschiedlicher Anzahl an Metallatomen. Trotzdem ist die entsprechende Chemie von Metallen der 5. Gruppe des Periodensystems nicht sehr gut erschlossen. Wir haben kurzlich uber die Synthese der anionisch

The Evolution of [{Ph2P(CH2)nPPh2}Pt(μ-S
✍ Rubén Mas-Ballesté; Gabriel Aullón; Paul A. Champkin; William Clegg; Claire Mégr 📂 Article 📅 2003 🏛 John Wiley and Sons 🌐 English ⚖ 304 KB

## Abstract Given the nucleophilicity of the {Pt~2~S~2~} ring, the evolution of [Pt~2~(μ‐S)~2~(P∩P)~2~] (P∩P=1,2‐bis(diphenylphosphino)ethane (dppe), 1,3‐bis(diphenylphosphino)propane (dppp)) metalloligands in the presence of the simplest electrophilic species, the proton, has been studied. Combine