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[Et4N][M(SCH2CH2S)3] (MNb, Ta), Homoleptic 1,2-Ethanedithiolate Complexes of Niobium and Tantalum

โœ Scribed by Dr. Kazuyuki Tatsumi; Yoitsu Sekiguchi; Prof. Dr. Akira Nakamura; Prof. Dr. Roger E. Cramer; Dr. John J. Rupp


Publisher
John Wiley and Sons
Year
1986
Tongue
English
Weight
272 KB
Volume
25
Category
Article
ISSN
0044-8249

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๐Ÿ“œ SIMILAR VOLUMES


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The reaction of [Cp\*MCl 4 ] (M ฯญ Nb, Ta; Cp\* ฯญ C 5 Me 5 ) with PH 2 R in toluene at room temperature gives the primary phosphine complexes [Cp\*MCl 4 (PH 2 R)] [Cp\* ฯญ C 5 Me 5 ; M ฯญ Nb: R ฯญ Bu t (1a), Ad (2a), Cy (3a), Ph (4a), 2,4,6-Me 3 C 6 H 2 (Mes) (5a); M ฯญ Ta: R ฯญ Bu t (1b), Ad (2b), Cy (3b

Triphospholes as 2e and 4e donors: Synth