A New Class of Tantalum(V) Dithiolate Complexes: Synthesis and Characterization of [Ta(η5-C5Me4R)(SCHCHS)2] (R = Me, Et) and [Ta(η5-C5Me5)(SCH2CH2S)2]
✍ Scribed by Dr. Kazuyuki Tatsumi; Junko Takeda; Yoitsu Sekiguchi; Masaki Kohsaka; Prof. Akira Nakamura
- Publisher
- John Wiley and Sons
- Year
- 1985
- Tongue
- English
- Weight
- 255 KB
- Volume
- 24
- Category
- Article
- ISSN
- 0044-8249
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The novel (ferriomethyl)-substituted silanols C 5 R 5 (OC) 2 Fe-CH 2 -SiMe(RЈ)OH [R = H, RЈ = Me (4a), Ph (4b); R = Me, RЈ = Me (4c)] are obtained by hydrolysis of the chloro(ferriomethyl)silanes C 5 R 5 (OC) 2 Fe-CH 2 -SiMe(RЈ)Cl [R = H, RЈ = Me (3a), Ph (3b); R = Me, RЈ = Me (3c)] in the presence
The reaction of [Cp\*MCl 4 ] (M ϭ Nb, Ta; Cp\* ϭ C 5 Me 5 ) with PH 2 R in toluene at room temperature gives the primary phosphine complexes [Cp\*MCl 4 (PH 2 R)] [Cp\* ϭ C 5 Me 5 ; M ϭ Nb: R ϭ Bu t (1a), Ad (2a), Cy (3a), Ph (4a), 2,4,6-Me 3 C 6 H 2 (Mes) (5a); M ϭ Ta: R ϭ Bu t (1b), Ad (2b), Cy (3b