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Synthesis and X-ray crystal structure of cis-(CO)4Cr[(Me3SiN)C(Ph)(NHPPh2)]

✍ Scribed by Wong Wai-Kwok; Jiang Tao; Daniel W.J. Kwong; Wong Wing-Tak


Publisher
Elsevier Science
Year
1995
Tongue
English
Weight
222 KB
Volume
14
Category
Article
ISSN
0277-5387

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Coordination chemistry / Ξ±-Imino ketones / CO complexes / Iron complexes The reaction of Fe 2 (CO) 9 at room temperature in THF or toluene with the Ξ±-imino ketones R 1 N=C(R 2 )-C(R 3 )=O (L) (R 1 = alkyl, R 2 = H, Me, Ph, R 3 = Me, Ph) (a-k), initially results in the formation of the mononuclear ch