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Synthesis and x-ray crystal structure of [li(c4h8o)4][ni(2,4,6-me3q6h2)3]

โœ Scribed by Robyn Hay-Motherwell; Geoffrey Wilkinson; Tracy K.N. Sweet; Michael B. Hursthouse


Publisher
Elsevier Science
Year
1996
Tongue
English
Weight
266 KB
Volume
15
Category
Article
ISSN
0277-5387

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2-(Me 2 NCH 2 )C 6 H 4 ]SnCl 3 (1) was prepared via (i) salt elimination reaction between RLi and SnCl 4 (1 : 1 molar ratio), in toluene solution, and (ii) redistribution reaction between [2-(Me 2 NCH 2 )C 6 H 4 ] 4 Sn and SnCl 4 (1 : 3 molar ratio), in the absence of a solvent. Recrystallization fr