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Synthesis and Characterization of [Sn8(2,6-Mes2C6H3)4] (Mes=2,4,6-Me3C6H2): A Main Group Metal Cluster with a Unique Structure

โœ Scribed by Barrett E. Eichler; Philip P. Power


Publisher
John Wiley and Sons
Year
2001
Tongue
English
Weight
76 KB
Volume
113
Category
Article
ISSN
0044-8249

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2-(Me 2 NCH 2 )C 6 H 4 ]SnCl 3 (1) was prepared via (i) salt elimination reaction between RLi and SnCl 4 (1 : 1 molar ratio), in toluene solution, and (ii) redistribution reaction between [2-(Me 2 NCH 2 )C 6 H 4 ] 4 Sn and SnCl 4 (1 : 3 molar ratio), in the absence of a solvent. Recrystallization fr