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Work of Adhesion of Synthetic Polypeptides Containing L-Lysine

✍ Scribed by H. Yamamoto; S. Ohara; H. Tanisho; K. Ohkawa; A. Nishida

Publisher
Elsevier Science
Year
1993
Tongue
English
Weight
189 KB
Volume
156
Category
Article
ISSN
0021-9797

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## Abstract Sequential polypeptides with the repeating units L‐tyrosyl‐L‐lysyl, L‐tyrosyl‐(L‐lysyl)~2~, and L‐tyrosyl‐(L‐lysyl)~3~ have been synthesized by solution polymerization of the __N__‐hydroxy‐succinimide esters of the corresponding di‐, tri‐, and tetrapeptides. The monomers for the polytri

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## Abstract Helix–coil transitions of poly(ε‐carbobenzyloxy L‐lysine) (PCBL) in __m__‐cresol and in mixtures of dichloroacetic acid (DCA) and ethylene dichloride (EDC) were investigated by optical rotation measurements, with special interest in the molecular‐weight dependence of helical content. Th

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We determined the apparent equilibrium constant of formation, KpH, of the Schijf bases of pyridoxal 5'-phosphate (PLP) and poly-and copolymers containing L-lysine, as a function of pH at 25" and a constant ionic strength of 0 . 1 ~. The KPH values obtained at acidic and neutral pH were larger that t

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## Abstract Poly(__N__^ε^‐stearyl‐L‐lysine) and poly(__N__^ε^‐pelargonyl‐L‐lysine) were synthesized both by polymerization of __N__^ε^‐pelargonyl and __N__^ε^‐stearyl‐L‐lysine NCA and by acylation of poly(L‐lysine) with pelargonyl and stearyl chloride. This second route has proven to be very useful