Vinylsilane mediated stereoselective total synthesis of (.+-.)-gymnomitrol
β Scribed by Han, Yeun-Kwei; Paquette, Leo A.
- Book ID
- 126445525
- Publisher
- American Chemical Society
- Year
- 1979
- Tongue
- English
- Weight
- 413 KB
- Volume
- 44
- Category
- Article
- ISSN
- 0022-3263
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π SIMILAR VOLUMES
Sumsrary: trans-Hydrindanediones (1, 3, and 15) have been synthesized in short steps through stereoselective introduction of vinylsilane units onto the cycloalkenones 5 OK 10 followed by AgBF4-mediated internal acylation of the vinylsilane moiety. We report here two of our syntheses of functionaliz
The stereoselectivity of iododesilylation of terminal E-vinylsilanes varies with changing amount of Lewis acid. The use of this "tunable" stereoselective reaction was demonstrated by the syntheses of two insect sex pheromones with defined E/Z isomeric ratios.